The Electronic Character of the π-Allylic Group of π-Allylic Palladium Complexes
نویسندگان
چکیده
منابع مشابه
Palladium Catalyzed Allylic Substitution of Acyloxypyrrolinones
Enantiomerically pure alkoxypyrrolinones have been shown to be facile building blocks for a variety of stereoselective syntheses involving Diels-Alder cycloadditions , 1,3dipolar reactions, conjugate additions, and acyliminium ion intermediates. In particular the application in the asymmetric synthesis of alkaloids based on N-acyliminium ion chemistry is of current interest. For example, (R)-1-...
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15 صفحه اولPalladium-catalyzed allylic alkenylation of allylic alcohols with n-butyl acrylate.
Various allylic alcohols reacted with n-butyl acrylate in the presence of p-toluenesulfonic anhydride and palladium catalysts to yield the corresponding n-butyl 2,5-dienoates with high regioselectivity.
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1971
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.44.2703